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Creators/Authors contains: "Kaufman, Darrell"

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  1. Abstract Ice-sheet volume during Marine Isotope Stage (MIS) 3 (57–29 ka) is controversial. Several recent studies have proposed that the Greenland Ice Sheet was smaller during MIS 3 than it is today based on radiocarbon ages of molluscan bivalve shells reworked into sedimentary deposits adjacent to the present ice margin. Such a result contrasts with available records of MIS 3 climate, ice volume, and sea level. We revisited a site previously interpreted as containing evidence for smaller than present ice during MIS 3. We collected marine bivalve shells and combined progressive acid dissolution in preparation for radiocarbon dating with new-generation amino acid analysis, which focuses on aspartic acid racemization. Our results suggest that contamination by young carbon yields finite radiocarbon ages despite bivalve shells likely dating to MIS 5e (∼125 ka) or even older. This result should be further tested, which could be accomplished with additional studies of this kind in combination with ice-sheet modeling and additional paleoclimate data generated from adjacent seas. 
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    Free, publicly-accessible full text available June 16, 2026
  2. Free, publicly-accessible full text available January 1, 2026
  3. ABSTRACT Bioerosion is a valuable tool for inferring palaeoenvironmental and palaeoclimatic changes over time and across different regions. However, studies of bioerosion traces are scarce in the Southern Hemisphere. Most ichnological studies within Argentina are concentrated in San Jorge Gulf (Patagonia, Argentina) and little is known about deposits located north of the Gulf. Here, we focus on bioerosion traces on Quaternary mollusc shells. Samples were collected from Quaternary marine deposits at the Bahía Vera–Cabo Raso sites in northern San Jorge Gulf. To resolve age discrepancies reported in the literature, we use amino acid racemization and radiocarbon dating to confirm the presence of beach ridge deposits from Marine Isotope Stage (MIS) 5 and MIS 1. Fourteen ichnotaxa are recorded in the study area. Additionally, distinct variations in the pattern of bioerosion across different ages are observed, indicating that environmental changes occurred in the northern San Jorge Gulf between the MIS 5 interglacial and the Holocene. This reinforces the hypothesis that there is an association between bioerosion, productivity and circulation in the Southern Atlantic Ocean. 
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    Free, publicly-accessible full text available April 1, 2026
  4. Free, publicly-accessible full text available December 1, 2025
  5. Three natural exposures near Healy, Alaska (Dry Creek, Panguingue Creek, and Healy Spur) and transects of shallow cores from three hillslopes near Eight Mile Lake were analyzed for particle-size distribution, loss-on-ignition for organic matter content, and radiocarbon dating. This study is part of a Master’s thesis research project by Walker at Northern Arizona University (https://www.proquest.com/openview/80b94829f88d5c8e0d0d678581079273/1?pq-origsite=gscholar&cbl=18750&diss=y). It builds on work of Marshall et al. (2023; doi: 10.1029/2022JG007290) who reported data from additional sediment cores taken along one of the hillslopes in this study, namely Hillslope A (https://arcticdata.io/catalog/view/doi:10.18739/A2F76683D). The motivation was to compare datasets of eolian material between different depositional settings, as well as identify trends in eolian thickness and particle size across the Healy landscape to reconstruct Holocene eolian deposition and identify the factors influencing depositon. 
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  6. Abstract Bioturbation can increase time averaging by downward and upward movements of young and old shells within the entire mixed layer and by accelerating the burial of shells into a sequestration zone (SZ), allowing them to bypass the uppermost taphonomically active zone (TAZ). However, bioturbation can increase shell disintegration concurrently, neutralizing the positive effects of mixing on time averaging. Bioirrigation by oxygenated pore-water promotes carbonate dissolution in the TAZ, and biomixing itself can mill shells weakened by dissolution or microbial maceration, and/or expose them to damage at the sediment–water interface. Here, we fit transition rate matrices to bivalve age–frequency distributions from four sediment cores from the southern California middle shelf (50–75 m) to assess the competing effects of bioturbation on disintegration and time averaging, exploiting a strong gradient in rates of sediment accumulation and bioturbation created by historic wastewater pollution. We find that disintegration covaries positively with mixing at all four sites, in accord with the scenario where bioturbation ultimately fuels carbonate disintegration. Both mixing and disintegration rates decline abruptly at the base of the 20- to 40-cm-thick, age-homogenized surface mixed layer at the three well-bioturbated sites, despite different rates of sediment accumulation. In contrast, mixing and disintegration rates are very low in the upper 25 cm at an effluent site with legacy sediment toxicity, despite recolonization by bioirrigating lucinid bivalves. Assemblages that formed during maximum wastewater emissions vary strongly in time averaging, with millennial scales at the low-sediment accumulation non-effluent sites, a centennial scale at the effluent site where sediment accumulation was high but bioturbation recovered quickly, and a decadal scale at the second high-sedimentation effluent site where bioturbation remained low for decades. Thus, even though disintegration rates covary positively with mixing rates, reducing postmortem shell survival, bioturbation has theneteffect of increasing the time averaging of skeletal remains on this warm-temperate siliciclastic shelf. 
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  7. Abstract Rapid Arctic warming this century will likely cause major water cycle and atmospheric circulation changes, including weakening mid‐latitude westerly winds and more persistent summer high pressures over Fennoscandia. These conditions can cause drought in northern Europe and extreme rainfall in the Mediterranean region. Uncertainties in the spatiotemporal patterns of these predictions can be partially addressed with records of past climate response to rapid change. The early Holocene collapse of the Northern Hemisphere ice sheets provides a natural experiment to evaluate the climate response to rapid changes in boundary conditions. We analyzed lipid biomarker distributions and hydrogen isotope (δ2H) values from Lake Imandra, Kola Peninsula, to infer Holocene summer temperature and summer precipitation δ2H values. Sensitivity tests of a lake model suggest summer precipitation δ2H values are the main mechanism influencing Lake Imandra δ2H values. Summer precipitation isotope values exhibited a nearly 20‰2H‐depletion between 8.6 and 8.0 ka, with2H ‐enriched values before 8.6 ka and2H ‐depleted values 8.0 ka to present. Maximum warmth occurred from 8.5 to 7.0 ka. Climate model experiments suggest that the early Holocene Laurentide Ice Sheet collapse caused a westward shift of the Fennoscandian summer high‐pressure center. This caused a decrease in the proportion of local,2H‐enriched precipitation falling throughout Fennoscandia and an increase in far‐traveled,2H‐depleted precipitation from the mid‐latitudes, circulation that persisted throughout the Holocene. These results illustrate the sensitivity of climate in Fennoscandia and show that circulation regime shifts can occur in response to changes in boundary conditions far upwind. 
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  8. Abstract Northern Arizona University, Flagstaff, Arizona, USA, recently installed a MIni CArbon DAting System (MICADAS) with a gas interface system (GIS) for determining the14C content of CO2gas released by the acid dissolution of biogenic carbonates. We compare 48 paired graphite, GIS, and direct carbonate14C determinations of individual mollusk shells and echinoid tests. GIS sample sizes ranged between 0.5 and 1.5 mg and span 0.1 to 45.1 ka BP (n = 42). A reduced major axis regression shows a strong relationship between GIS and graphite percent Modern Carbon (pMC) values (m = 1.011; 95% CI [0.997–1.023], R2= 0.999) that is superior to the relationship between the direct carbonate and graphite values (m = 0.978; 95% CI [0.959-0.999], R2= 0.997). Sixty percent of GIS pMC values are within ±0.5 pMC of their graphite counterparts, compared to 26% of direct carbonate pMC values. The precision of GIS analyses is approximately ±7014C yrs to 6.5 ka BP and decreases to approximately ±13014C yrs at 12.5 ka BP. This precision is on par with direct carbonate and is approximately five times larger than for graphite. Six Plio-Pleistocene mollusk and echinoid samples yield finite ages when analyzed as direct carbonate but yield non-finite ages when analyzed as graphite or as GIS. Our results show that GIS14C dating of biogenic carbonates is preferable to direct carbonate14C dating and is an efficient alternative to standard graphite14C dating when the precision of graphite14C dating is not required. 
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  9. The role of high latitude lakes in storing and processing terrestrial organic carbon export is not well understood. We analyzed a 2.7-meter (m) -long sedimentary record from Eight Mile Lake that extends back 15,700 years to evaluate connections between productivity, organic carbon accumulation and late Quaternary environmental change in central Alaska. We analyzed macrofossil radiocarbon, alongside physical and biogeochemical properties. This dataset includes data from 12 sediment cores collected across Eight Mile Lake. These cores span time frames of 1000 - 15,700 years. This dataset includes bulk physical data, organic matter abundance, biogenic silica abundance, particle size, geochronological information, magnetic susceptibility data and hyperspectral imagery. 
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  10. Using paleoecological data to inform resource management decisions is challenging without an understanding of the ages and degrees of time-averaging in molluscan death assemblage (DA) samples. We illustrate this challenge by documenting the spatial and stratigraphic variability in age and time-averaging of oyster reef DAs. By radiocarbon dating a total of 630 oyster shells from samples at two burial depths on 31 oyster reefs around Florida, southeastern United States, we found that (1) spatial and stratigraphic variability in DA sample ages and time-averaging is of similar magnitude, and (2) the shallow oyster reef DAs are among the youngest and highest-resolution molluscan DAs documented to date, with most having decadal-scale time-averaging estimates, and sometimes less. This information increases the potential utility of the DAs for habitat management because DA data can be placed in a more specific temporal context relative to real-time monitoring data. More broadly, the results highlight the potential to obtain decadal-scale resolution from oyster bioherms in the fossil record. 
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